A Dictionary of Arts: Thenard's Blue, or Cobalt blue.

A Dictionary of Arts, Manufactures, and Mines; containing A Clear Exposition of Their Principles and Practice

by Andrew Ure, M. D.;
F. R. S. M. G. S. Lond.: M. Acad. M. S. Philad.; S. PH. DOC. N. GERM. Ranow.; Mulh. Etc. Etc.

Illustrated with nearly fifteen hundred engravings on wood
Eleventh American, From The Last London Edition.
To which is appended, a Supplement of Recent Improvements to The Present Time.

New York: D Appleton & company, 200 Broadway. Philadelphia: George S. Appleton, 148 Chestnut St.
MDCCCXLVII

1847

THENARD's BLUE, or COBALT BLUE, is prepared by digesting the oxide of cobalt used in the potteries, with nitric acid, evaporating the nitrate almost to dryness, diluting it with water, and filtering, to separate some arseniate of iron, which usually precipitates. The clear liquor is to be poured into a solution of phosphate of soda, whence an insoluble phosphate of cobalt falls. This being well washed, is to be intimately mixed in its soft state with eight times its weight of well-washed gelatinous alumina, which has been obtained by pouring a solution of alum into water of ammonia in excess. The uniformly coloured paste is to be spread upon plates, dried in a stove, then bruised dry in a mortar, enclosed in a crucible, and subjected to a cherry-red heat for half an hour. On taking out the crucible, and letting it cool, the fine blue pigment is to be removed into a bottle, which is to be stopped till used.

The arseniate of cobalt may be substituted, in the above process, for the phosphate, but it must be mixed with sixteen times its weight of the washed gelatinous alumina. The arseniate is procured by pouring the dilute nitrate of cobalt into a solution of arseniate of potassa. If nitrate of cobalt be mixed with the alumina, and the mixture be treated as above described, a blue pigment will also be obtained, but paler than the preceding, showing that the colour consists essentially of alumina stained with oxide of cobalt.